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Article Details

  • Article Code : FIRAT-AKADEMI-10455-5636
  • Article Type : Araştırma Makalesi
  • Publication Number : 1A0487
  • Page Number : 55-71
  • Doi : 10.12739/NWSA.2023.18.4.1A0487
  • Abstract Reading : 219
  • Download : 41
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Issue Details

  • Year : 2023
  • Volume : 18
  • Issue : 4
  • Number of Articles Published : 1
  • Published Date : 1.10.2023

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Engineering Sciences

Serial Number : 1A
ISSN No. : 1308-7231
Release Interval (in a Year) : 4 Issues

REMOVAL OF MALACHITE GREEN DYE FROM AQUEOUS SOLUTION USING Verbascum Thapsus L.

Ferhat SİME1 , Zehra ORDU2 , Mohammed Abdul FATTAH SALEH3 , MUTLU YALVAÇ4

Humans are the only producers of wastes accumulated in nature. Treatment technologies are developing by following, analyzing and imitating nature. Herbal bioadsorbents are natural substances used in wastewater treatment. In this study, Malachite Green (MG) was removed from the water with Verbascum Thapsus L. (VTL). VTL collected from Mount Ararat is a wild and invasive plant. SEM, BET and FTIR were used to determine adsorbent characterization. Experimental design was made with the surface response method (RSM). Optimum values obtained as a result of experimental studies: Adsorbent mass is 0.75g, pH6.5, initial concentration of adsorbed substance is 304mg/L and contact time of adsorption is 40 minutes. It was determined that the adsorption process was carried out in accordance with the Langmuir isotherm (R2=0.9997) and the second-order kinetic model (R2=0.9997). The maximum adsorbent capacity is 38.85 mg/g and the dye removal efficiency is 95%. As a result of the thermodynamic study; Gibbs free energy (?G) was found to be negative for all temperatures. According to the results obtained at the end of the study, it was found that VTL is an effective adsorbent that can be used in chemical adsorption to remove MG from aqueous solution.

Keywords
Adsorption, Verbascum Thapsus L. (VTL), Surface Response Method (RSM) , Malachite Green , Bioadsorbent,

Details
   

Authors

Ferhat SİME (1)

ferhatsime04@gmail.com | 0000-0002-4925-5982

Zehra ORDU (2) (Corresponding Author)

mersin üniversitesi
z.ordu02@gmail.com | 0000-0003-3964-1203

Mohammed Abdul FATTAH SALEH (3)

NARC
muh.saleh89@gmail.com | 0000-0002-3145-4457

MUTLU YALVAÇ (4)

Mersin Üniversitesi
myalvac@mersin.edu.tr | 0000-0002-1281-5712

Supporting Institution

: mersin üniversitesi bilimsel araştırma projeleri

Project Number

: 2020-1-TP2-3849

Thanks

: Teşekkürler Finansman: Bu çalışma[INJ] Mersin Üniversitesi Bilimsel Araştırma Projeleri Birimi tarafından mali olarak desteklenmiştir. [INJ]Proje numarası: 2020-1-TP2-3849[INJ]
References
[1] Vakili, M., Rafatullah, M., Salamatinia, B., Abdullah, A.Z., Ibrahim, M.H., Tan, K.B., Gholami, Z., and Amouzgar, P., (2014). Application of chitosan and its derivatives as adsorbents for dye removal from water and wastewater: A review. Carbohydrate Polymers, 113:115-130.

[2] Han, D., Zhao, H., Gao, L., Qin, Z., Ma, J., Han, Y., and Jiao, T., (2021). Preparation of carboxymethyl chitosan/phytic acid composite hydrogels for rapid dye adsorption in wastewater treatment. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 628.

[3] Garba, Z.N., Zhou, W., Lawan, I., Xiao, W., Zhang, M., Wang, L., Chen, L., and Yuan, Z., (2019). An overview of chlorophenols as contaminants and their removal from wastewater by adsorption: A review. Journal of Environmental Management, 241:59-70.

[4] Lu, Y., Song, S., Wang, R., Liu, Z., Meng, J., Sweetman, A.J., Jenkins, A., Ferrier, R.C., Li, H., Luo, W., and Wang, T., (2015). Impacts of soil and water pollution on food safety and health risks in China. Environment International, 77:5-15.

[5] Xiao, W., Jiang, X., Liu, X., Zhou, W., Garba, Z.N., Lavan, I., Wang, L., and Yuan, Z., (2021). Adsorption of organic dyes from wastewater by metal-doped porous carbon materials. Journal of Cleaner Production.

[6] Lourenço, N., Novais, J., and Pinheiro, H., (2001). Effect of some operational parameters on textile dye biodegradation in a sequential batch reactor. Journal of Biotechnology, 89(2-3):163-174.

[7] Salih, S.J., Kare, A.S., and Anwer, S.S., (2022). Adsorption of anionic dyes from textile wastewater utilizing raw corncob. Heliyon, 8(8):e10092.

[8] Chen, Q., Zhang, Q., Yang, Y., Wang, Q., He, Y., and Dong, N., (2021). Synergetic effect on methylene blue adsorption to biochar with gentian violet in dyeing and printing wastewater under competitive adsorption mechanism. Case Studies in Thermal Engineering, 26:101099.

[9] Gupta, V.K., Kumar, R., Nayak, A., Saleh, T.A., and Barakat, M., (2013). Adsorptive removal of dyes from aqueous solution onto carbon nanotubes: A review. Advances in Colloid and Interface Science, 1(193-194):24-34.

[10] Wang, C.C., Juang, L.C., Hsu, T.C., Lee, C.K., Lee, J.F., and Huang, F.C., (2004). Adsorption of basic dyes onto montmorillonite. Journal of Colloid and Interface Science, 273(1):80-86.

[11] Lee, C.K., Wang, C.C., Juang, L.C., Lyu, M.D., Hung, S.H., and Liu, S.S., (2008). Effects of sodium content on the microstructures and basic dye cation exchange of titanate nanotubes. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1(1-3):164-173.

[12] Cheng, S., Zhao, S., Xing, B., Liu, Y., Zhang, C., and Xia, H., (2022). Preparation of magnetic adsorbent-photocatalyst composites for dye removal by synergistic effect of adsorption and photocatalysis. Journal of Cleaner Production, 348:131301.

[13] Soh, E.Y., Lim, S.S., Chew, K.W., Phuang, X.W., Ho, W.M., Chu, K.Y., Wong, R.R., and Lee, L.Y., (2022). Valorization of spent brewery yeast biosorbent with sonication-assisted adsorption for dye removal in wastewater treatment. Environmental Research, 204:112385.

[14] Ramutshatsha-Makhwedzha, D., Mavhungu, A., Moropeng, M.L., and Mbaya, R., (2022). Activated carbon derived from waste orange and lemon peels for the adsorption of methyl orange and methylene blue dyes from wastewater. Heliyon, 8(8):e09930.

[15] Shoori, I.S., Jorabchi, M.N., Ghasemi, S., Golriz, M., Wohlrab, S., and Khonakdar, H.A., (2023). Advancements in wastewater Treatment: A computational analysis of adsorption characteristics of cationic dyes pollutants on amide Functionalized-MOF nanostructure MIL-53 (Al) surface. Separation and Purification Technology, 319:124081.

[16] Wong, S., Ngadi, N., Inuwa, I.M., and Hassan, O., (2018). Recent advances in applications of activated carbon from biowaste for wastewater treatment: A short review. Journal of Cleaner Production, 175:361-375.

[17] Khorram, A.G. and Fallah, N., (2018). Treatment of textile dyeing factory wastewater by electrocoagulation with low sludge settling time: Optimization of operating parameters by RSM. Journal of Environmental Chemical Engineering, 6(1):635-642.

[18] Momina, K.A., (2023). Feasibility of the adsorption as a process for its large scale adoption across industries for the treatment of wastewater: Research gaps and economic assessment. Journal of Cleaner Production, 388:136014.

[19] Davoodbeygi, Y., Askari, M., Salehi, E., and Kheirieh, S., (2023). A review on hybrid membrane-adsorption systems for intensified water and wastewater treatment: Process configurations, separation targets, and materials applied. Journal of Environmental Management, 335:117577.

[20] Al-Gorair, A.S., (2019). Treatment of wastewater from cationic dye using eco-friendly nanocomposite: Characterization, adsorption and kinetic studies. The Egyptian Journal of Aquatic Research, 45(1):25-31.

[21] Salahshoori, I., Jorabchi, M.N., Ghasemi, S., Golriz, M., Wohlrab, S., and Khonakdar, H.A., (2023). Advancements in wastewater Treatment: A computational analysis of adsorption characteristics of cationic dyes pollutants on amide Functionalized-MOF nanostructure MIL-53 (Al) surfaces. Separation and Purification Technology, 319:124081.

[22] Aljohani, M.M., Al-Qahtani, S.D., Alshareef, M., El-Desouky, M.G., El-Bindary, A.A., El-Metwaly, N.M., and El-Bindary, M.A., (2023). Highly efficient adsorption and removal bio-staining dye from industrial wastewater onto mesoporous Ag-MOFsHighly efficient adsorption and removal bio-staining dye from industrial wastewater onto mesoporous Ag-MOFs. Process Safety and Environmental Protection, 172:395-407.

[23] Liu, Z., Huang, X., Miao, Y., Gao, B., Shi, Y., Zhao, J., and Tan, S.H., (2022). Eggplant biomass based porous carbon for fast and efficient dye adsorption from wastewater. Industrial Crops and Products, 187(B):115510.

[24] Dey, P., Mahapatra, B., Juyal, V., Pramanick, B., Negi, M., Paul, J., and Singh, S., (2021). Flax processing waste – A low-cost, potential biosorbent for treatment of heavy metal, dye and organic matter contaminated industrial wastewater. Industrial Crops and Products, 174:114195.

[25] Laverde, M.P., Salamanca, M., Diaz-Corrales, J.D., Flórez, E., Agredo, J.S., and Torres-Palma, R.A., (2021). Understanding the removal of an anionic dye in textile wastewaters by adsorption on ZnCl2 activated carbons from rice and coffee husk wastes: A combined experimental and theoretical study. Journal of Environmental Chemical Engineering, 9(4):105685.

[26] Özacar, M. and Şengil, I., (2004). Two-stage batch sorber design using second-order kinetic model for the sorption of metal complex dyes onto pine sawdust. Biochemical Engineering Journal, 21(1):39-45.

[27] Yadav, J., Sahu, O., and Marwah, H., (2022). Bioadsorption of dye from textile effluent with surface response methodology. Materialstoday proceedings, 68(4):937-942.

[28] Besegatto, S.V., Martins, M.L., Lopes, T.J., Adriano, A., and Silva, A.D., (2021). Multivariated calibration as a tool for resolution of color from mandarin peel and dyes in aqueous solution for bioadsorption studies. Journal of Environmental Chemical Engineering, 9(1):104605.

[29] Sahu, O. and Singh, N., (2019). 13 - Significance of bioadsorption process on textile industry wastewater. The Impact and Prospects of Green Chemistry for Textile Technology, 367-416.

[30] Obayomi, K.S., Lau, S.Y., Danqual, M.K., Zhang, J., Chiong, T., Meunier, L., Gray, S.R., and Mahmudur, M.R., (2023). Green synthesis of graphene-oxide based nanocomposites for efficient removal of methylene blue dye from wastewater. Desalination, 564:116749.

[31] El-Kammah, M., Elkhatib, E., Gouveia, S., Cameselle, C., and Aboukila, E., (2022). Cost-effective ecofriendly nanoparticles for rapid and efficient indigo carmine dye removal from wastewater: Adsorption equilibrium, kinetics and mechanism. Environmental Technology & Innovation, 28:102595.

[32] Ahmad, R. and Kumar, R., (2010). Adsorption studies of hazardous malachite green onto treated ginger waste. Journal of Environmental Management, 91(4):1032-1038.

[33] Bekçi, Z., Özveri, C., Yoldaş, S., and Yurdak, K., (2008). Sorption of malachite green on chitosan bead. Journal of Hazardous Materials, 154(1-3):254-261.

[34] Weldegebrieal, G.K., (2020). Photocatalytic and antibacterial activityof CuO nanoparticles biosynthesized using Verbascum thapsus leaves extract. Optik, 204.

[35] Prakash, V., Rana, S., and Sagar, A., (2016). Studies on Antibacterial Activity of Verbascum. Journal of Medicinal Plants Studies, 4(3):101-104.

[36] Okasha, Y.M., Fathy, F.I., Soliman, F.M., and Fayek, N.M., (2023). The untargeted phytochemical profile of Verbascum thapsus L. with potent antiviral, antibacterial and anticancer activities. South African Journal of Botany, 156:334-341.

[37] Elemike, E.E., Onwudiwe, D.C., and Mkhize, Z., (2016). Eco-friendly synthesis of AgNPs using Verbascum thapsus extract and its photocatalytic activity. Materials Letters, 185:452-455.

[38] Saleh, M., Işık, Z., Aktaş, Y., Arslan, H., Yalvaç, M., and Dizge, N., (2021). Green synthesis of zero valent iron nanoparticles using Verbascum thapsus and its Cr (VI) reduction activity. Bioresource Technology Reports, 13.

[39] Yadav, J. and Sahu, O., (2023). Malachite green dye purification from effluent using synthesized ceramic clay: Characterisation; optimization and scale up. Ceramics International, 49(15):24831-24851.

[40] Hashem, A.A., Mahmoud, S.A., Geioushy, R.A., and Fouad, O.A., (2023). Adsorption of malachite green dye over synthesized calcium silicate nanopowders from waste materials. Materials Science and Engineering: B, 295.

[41] Wolska, J., Munko, M., EL Siblani, H., Igor, T., Frankowski, M., Szwajca, A., Walkowiak-Kulikowska, J., El-Roz, M., and Wolski, L., (2023). The influence of cross-linking density on the efficiency of post-synthetic sulfonation of hyper-cross-linked polymers and their adsorption capacity for antibiotic pollutants. Journal of Environmental Chemical Engineering, 11(5):110429.

[42] Onu, C.E., Nwabanne, J.T., Ohale, P.E., and Asadu, C.O., (2021). Comparative analysis of RSM, ANN and ANFIS and the mechanistic modeling in eriochrome black-T dye adsorption using modified clay. South African Journal of Chemical Engineering, 36:(24-42).